Search results for "Ethylene bis"

showing 4 items of 4 documents

DFT computational study on Fe(III)-N,N′-ethylene-bis(salicylideneiminato) derivatives

2005

DFT calculations, at unrestricted B3LYP level, have been performed on the structures of three iron(III) complexes, Fe(Salen)Cl, [Fe(Salen)]+ and [Fe(Salen)OH2]+, where Salen is the anion of Schiff base ligand N,N′-ethylene-bis (salicylideneimine), considering the spin multiplicity (S) values 2, 4 and 6. The results obtained have been compared with the available structural an magnetic experimental data, allowing us to conclude that a stable form of the FeIII(Salen) complex in aqueous solution should be characterized by an energy stabilization of the S=4 compared to the S=6 state.

Aqueous solutionSchiff baseLigandInorganic chemistryCondensed Matter PhysicsBiochemistryIonEthylene bisCrystallographychemistry.chemical_compoundchemistryMetal salen complexesPhysical and Theoretical ChemistryIron Schiff bases Salen Density functional calculationsSettore CHIM/02 - Chimica Fisica
researchProduct

Heterogeneous response to differentiation induction with different polar compounds in a clonal rat rhabdomyosarcoma cell line (BA-HAN-1C)

1989

The clonal rat rhabdomyosarcoma cell line BA-HAN-1C was tested for its susceptibility to differentiation induction with different polar compounds. This cell line is composed of proliferating mononuclear tumour cells, some of which spontaneously fuse to form terminally differentiated postmitotic myotube-like giant cells. Exposure of BA-HAN-1C cells to dimethylsulphoxide (DMSO), hexamethylene bisacetamide (HMBA), sodium butyrate (NaBut) and N-monomethylformamide (NMF) resulted in a significant inhibition of proliferation (P less than 0.001) and in a simultaneous increase in differentiation. The response was most pronounced after exposure to NMF as evidenced by a marked increase in the creatin…

Cancer ResearchCellular differentiationAntineoplastic AgentsBiologyPeripheral blood mononuclear cellHexamethylene bisacetamideCell LineCell Fusionchemistry.chemical_compoundAcetamidesRhabdomyosarcomaTumor Cells CulturedAnimalsDimethyl SulfoxideCreatine KinaseCell fusionFormamidesDimethyl sulfoxideCell DifferentiationSodium butyrateMolecular biologyClone CellsRatsButyratesOncologychemistryBiochemistryCell cultureGiant cellButyric AcidResearch ArticleBritish Journal of Cancer
researchProduct

Cytokines with Possible Clinical Utility

1987

Biological response modifiers (BRM) are agents aimed at reducing tumor growth, not primarily by exerting direct cytotoxic effects but by modulation of tumor gene expression (e.g., induction of differentiation) or by enhancing host defense mechanisms directed against cancer cells. BRM as primary therapy or as adjuncts to cytotoxic agents in the treatment of cancers have attracted increasing interest in view of stagnating clinical results in many areas [1], and there is increasing evidence of in vitro and in vivo efficacy of these agents. Furthermore, advances in molecular biology suggesting that oncogenes and their products play a crucial role in oncogenesis support approaches to modulation …

In vivoCancer cellCancer researchmedicineCytotoxic T cellBiological response modifiersBiologyCytotoxicityCarcinogenesismedicine.disease_causeHexamethylene bisacetamideIn vitro
researchProduct

Optimisation of liquid rubber modified bitumen for road pavements and roofing applications

2020

Abstract Polymer Modified Bitumens (PMBs) are largely used for pavement and roofing membranes applications with Styrene-Butadiene-Styrene Block copolymer (SBS) playing a major role in both markets despite its constantly increasing price due to the rising demand for quality bitumen modifiers. On the other hand, there is an increasing trend of recycling end of life tyres generating Recycled Tyre Rubber (RTR) at affordable price. This investigation aims at engineering a modified bitumen with a combination of Liquid Rubber (LR), a homogeneous blend of 50–70% RTR pre-processed in combination with heavy oils, and a wax denominated Ethylene Bis Stearamide (EBS). In the first phase, the effect of L…

Recycled tyre rubberMaterials science0211 other engineering and technologiesEBS020101 civil engineering02 engineering and technologyAsphalt mixtures0201 civil engineeringEthylene bischemistry.chemical_compoundResponse surface methodologyNatural rubberRheology021105 building & constructionGeneral Materials ScienceResponse surface methodologyComposite materialCivil and Structural EngineeringPolymer modifiedWaxBuilding and ConstructionRoofing membranesLiquid rubberchemistryAsphaltLiquid rubbervisual_artvisual_art.visual_art_mediumSBS modified bitumenConstruction and Building Materials
researchProduct